01whole.pdf (6.58 MB)
Download file

Controls on organic carbon enrichment in a Permian periglacial setting (Arckaringa Basin)

Download (6.58 MB)
thesis
posted on 28.03.2022, 11:50 by Natalie Debenham
In the Arckaringa Basin, organic carbon (OC) enrichment within the Permo-Carboniferous Stuart Range Formation occurred within syn-sedimentary fault troughs that were scoured by glaciers. This enrichment was facilitated by sytematic variations in water chemistry within these troughs identifying periods of restriction and open water exchange with the ocean to the south. The U-shaped morphology of some of these troughs apparent in seismic profiles along with the presence of lonestones, dropstones, and feldspathic, angular sediment identifies a cold palaeoclimate depositional setting that is unusual for the organic enrichments of up to 12% total organic carbon (TOC). It is hypothesised that episodic restriction within these fjord-like troughs led to cyclical variations in sulphur concentration within the water column, driving sulfurization reactions that preserved organic matter in discreet laminae. Abundant pyrite (up to 20 wt%) and the distribution of organosulphur compounds with TOC supports this hypothesis. Cyclical oxygenation of bottom waters and alkalinity from OM mineralisation by bacterial sulphate reducers resulted in the formation of manganese carbonate (kutnohorite) during periods of ventilation. Organic-lean sediments in the adjacent lacustrine Cooper Basin that lacked a source of marine sulphur do not show vulcanization nor preservation of labile organic matter.

History

Notes

Theoretical thesis. Bibliography: pages 49-54

Awarding Institution

Macquarie University

Degree Type

Thesis MRes

Degree

MRes, Macquarie University, Faculty of Science and Engineering, Department of Earth and Planetary Sciences

Department, Centre or School

Department of Earth and Planetary Sciences

Year of Award

2015

Principal Supervisor

Martin Kennedy

Additional Supervisor 1

Stefan C. Loehr

Rights

Copyright Natalie Debenham 2015. Copyright disclaimer: http://www.copyright.mq.edu.au

Language

English

Jurisdiction

Australia

Extent

1 online resource (1, 65 pages) illustrations (some colour), colour maps

Former Identifiers

mq:44678 http://hdl.handle.net/1959.14/1071241